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| 研究生： |
曾思瑜 Tseng, Ssu-Yu |
|---|---|
| 論文名稱： |
含釕化合物修飾碳管探討：光控磁性AFM探針製備研究 Ruthenium Complex Modified Photomagnetic Carbon Nanotube：Applications and Characterizations. |
| 指導教授： |
王忠茂
Wang, Chong-Mou |
| 學位類別： |
碩士 Master |
| 系所名稱： |
化學系 Department of Chemistry |
| 論文出版年： | 2016 |
| 畢業學年度： | 104 |
| 語文別： | 中文 |
| 論文頁數： | 61 |
| 中文關鍵詞： | 2,2’-二吡啶-5-胺基菲繞啉釕化合物 、多壁奈米碳管 、磁性原子力顯微術 、光磁轉換 |
| 英文關鍵詞： | Ru(bpy)2(NH2-phen)2+, multi-walled carbon nanotube, photomagnetic |
| DOI URL： | https://doi.org/10.6345/NTNU202204294 |
| 論文種類： | 學術論文 |
| 相關次數： | 點閱：82 下載：2 |
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我們以Ru(bpy)2Cl2和NH2-phen合成Ru(bpy)2(NH2-phen)2+，再以偶氮還原修飾法將此錯合物鍵結於多壁奈米碳管和HOPG表面，成為Ru@CNT、Ru@HOPG。經由磁性分析，我們發現在室溫下2,2’-二吡啶-5-胺基菲繞啉釕化合物、Ru@CNT與Ru@HOPG受到473-nm雷射光照射時，會顯現光磁性。我們進而以之製備具有光磁轉換功能的磁性原子力顯微術(MFM)掃瞄探針，以分析磁性物質表面。有鑒於市售MFM探針易被氧化，不易保存，於磁性物質分析上存在困擾，故若以2,2’-二吡啶-5-胺基菲繞啉釕化合物製備MFM探針，將可有效避免除此一困擾。
We synthesized Ru(bpy)2(NH2-phen)2+ by reacting Ru(bpy)2Cl2 with 1,10-phenanthrolin-5-amine (NH2-phen), and then attached the resulting product on multi-walled carbon nanotube and highly oriented pyrolytic graphite (HOPG) through diazotization/denitrogenation processes. We found that Ru(bpy)2(NH2-phen)2+ and the resulting Ru@CNT and Ru@HOPG exhibited magnetism as exposed to the 473-nm light at room temperature. In view of the fact that most metal-coated magnetic-mode AFM (MFM) tips are prone to oxidation in the air, we then devoted efforts to modifying Ru(bpy)2(NH2-phen)2+ on commercial silicon-based tips to fabricate photomagnetic AFM tips. The resultant tips show application potential in MFM imaging.
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