本研究為探討廢棄物焚化廠焚化衍生飛灰中戴奧辛類化合物分佈、毒性當量及特徵剖面。結果顯示，廢棄物焚化爐（MSWI）和事業廢棄物焚化爐（IWI）兩廠之袋式灰與混合灰PCDD/Fs濃度皆以OCDD濃度最高物種，MSWI袋式灰和混合灰濃度分別為1.44 ng/g和1.31 ng/g，IWI袋式灰和混合灰濃度分別為0.0213±0.00546 ng/g和0.0200±0.00759 ng/g，兩廠之袋式灰與混合灰中PCDFs濃度均大於PCDDs，表示戴奧辛類生成機制皆為De Novo反應大於Precursor反應。MSWI袋式灰與混合灰毒性當量濃度分別為0.0657 ng WHO -TEQ/g和0.0357 ng WHO -TEQ/g，IWI袋式灰與混合灰毒性當量濃度分別為1.42×10-3±2.40×10-4 ng WHO -TEQ/g和7.69×10-4±1.32×10-4 ng WHO -TEQ/g。MSWI袋式灰與混合灰毒性當量濃度分別為0.0786 ng WHO -TEQ/g和0.0317 ng WHO -TEQ/g，IWI袋式灰與混合灰毒性當量濃度分別為3.13E×10-3±4.19×10-4 ng WHO -TEQ/g和1.70×10-3±4.42×10-4 ng WHO -TEQ/g。毒性主要貢獻物皆為PCDFs，其次為PCDDs、DL-PCBs。MSWI污防前與袋式灰之PCDD和PCDF比值皆小於1，表示兩者戴奧辛類生成機制相同為De Novo反應大於Precursor反應；排放管道與袋式灰之PCDD和PCDF比值不相似，排放管道戴奧辛類生成機制為Precursor反應大於De Novo反應。IWI污防前、排放管道和袋式灰之PCDD和PCDF比值不相似，表示戴奧辛類生成機制不相似，IWI污防前和排放管道戴奧辛類生成機制為Precursor反應大於De Novo反應；IWI袋式灰戴奧辛類生成機制相似為De Novo反應大於Precursor反應。利用微環境模式模擬兩座焚化廠之袋式集塵器之戴奧辛化合物分佈，發現到實際值和模擬值的濃度趨勢MSWI較IWI相似。

This study investigate the distribution of dioxins in the incineration-derived fly ash of waste incineration plants. The results showed that the PCDD/Fs concentrations of baghouse filter ash and mixed ash from municipal solid waste incineration（MSWI）and industrial waste incineration（IWI）has the highest concentration of OCDD. The concentrations of MSWI baghouse filter ash and mixed ash were 1.44 ng/g and 1.31 ng/g respectively, while the concentrations of IWI baghouse filter ash and mixed ash were 0.0213±0.00546 ng/g and 0.0200±0.00759 ng/g respectively. The PCDFs concentrations in the baghouse filter ash and mixed ash of the two plants were both higher than PCDDs concentrations, indicating that the formation mechanism of dioxin-like is more in line with De Novo reaction than Precursor reaction. The PCDD/Fs concentrations of MSWI baghouse filter ash and mixed ash were 0.0657 ng WHO -TEQ/g and 0.0357 ng WHO -TEQ/g respectively, while the concentrations of IWI baghouse filter ash and mixed ash were 1.42×10-3±2.40×10-4 ng WHO-TEQ/g and 7.69×10-4±1.32×10-4 ng respectively. The PCDD/Fs TEQ concentrations in MSWI baghouse filter ash and mixed ash were 0.0786 ng WHO -TEQ/g and 0.0317 ng WHO-TEQ/g respectively, while the TEQ concentrations of IWI baghouse filter ash and mixed ash were 3.13E×10-3±4.19×10-4 ng WHO-TEQ/g and 1.70×10-3±4.42×10-4 ng WHO-TEQ/g respectively. PCDFs has a higher toxicity contribution proportion in ash, followed by PCDDs and PCBs. The ratios of PCDD and PCDF between MSWI pre-fouling and baghouse filter ash were below 1, indicated that they have the same dioxin-like generation mechanism, which is more in line with the De Novo Synthesis than the Precursor reaction, while the ratios of PCDD and PCDF between the discharge pipelines and baghouse filter ash were different, indicated that the dioxin-like generation mechanism is more in line with the Precursor reaction than the De Novo Synthesis. The PCDD and PCDF ratios of IWI pre-fouling, discharge pipelines and baghouse filter ash were different, indicated that they have different generation mechanism of dioxin-like. The generation mechanism of dioxin-like of IWI pre-fouling and discharge pipeline is more in line with the Precursor Reaction than the De Novo Synthesis; while the generation mechanism of dioxin-like of IWI baghouse filter ash is more in line with the De Novo Synthesis than the Precursor reaction. The micro-environment model is used to simulate the distribution of dioxin compounds in baghouse filter ash collectors of two incineration plants, it demonstrates that the actual concentration trend and the stimulated concentration trend of MSWI was similar as compared to IWI.

朱信，簡聰文，2002，「燃燒與空氣污染物」，科學發展，第355期，行政院國家科學委員會，第18~21頁
朱翊慈，2018，逸壓模式對類戴奧辛化合物之分佈應用研究，碩士論文，國立屏東科技大學，環境工程與科學系所，屏東。
行政院環保署，1991，「垃圾處理方案」。
余宗賢，2004，固化法於飛灰重金屬及戴奧辛之穩定化研究，碩士論文，國立高雄第一科技大學，環境與安全衛生工程所，高雄。
李彥芬，2004，戴奧辛類化合物於飛灰中之生成與控制研究，碩士論文，國立屏東科技大學，環境工程與科學系所，屏東。
宋德高，1995，臺灣地區環境中含氯毒性有機化合物分析研究，碩士論文，國立清華大學，化學研究所，新竹。
吳宛錚，2006，Photo-Fenton程序降解絕緣油中多氯聯苯之研究，碩士論文，國立屏東科技大學，環境工程與科學系所，屏東。
許菁芳，2000，油症患者血液中多氯聯苯、多氯戴奧辛、多氯夫喃同源物濃度與肝功能異常之相關性研究，碩士論文，國立成功大學環境醫學研究所，台南。
章裕民，1996，焚化處理技術，文京圖書公司，台北。
陳宏明，2019，粉狀活性碳噴注及袋式集塵效率對戴奧辛類化合物於廢棄物焚化設施中質量分佈之影響，碩士論文，國立屏東科技大學，環境工程與科學系所，屏東。
陳宜伶，2002，氧化鈦（Ⅳ）覆鍍方法對多氯聯苯光催化效應之影響，碩士論文，國立屏東科技大學，環境工程與科學系所，屏東。
陳建呈，2009，前驅物對戴奧辛類化合物催化生成效應之研究，碩士論文，國立屏東科技大學，環境工程與科學系所，屏東。
楊宜寧，2004，高屏溪河口與近岸海域沉積物中多氯聯苯與六氯苯化合物含量分析之研究，碩士論文，國立中山大學，海洋環境及工程學系研究所，高雄。
劉肇昀，2014，調查石化工業區周界養殖漁塭之類戴奧辛化合物，碩士論文，國立屏東科技大學，環境工程與科學系研究所，屏東。
錢建嵩，2010，「流體化床焚化爐與戴奧辛控制」，科學發展，450期，行政院國家科學委員會，第12-19頁。
謝函潔，2001，垃圾焚化飛灰吸附有機物與重金屬鉛、鎘的探討，碩士論文，國立臺灣大學，環境工程學研究所，台北。
Altarawneh, M., Dlugogorski, B. Z., Kennedy, E. M., and Mackie, J. C., 2009, “Mechanisms for formation, chlorination, dechlorination and destruction of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs),” Progress in Energy and Combustion Science, Vol. 35(3), pp. 245-274.
Ballschmiter, K., Braunmiller, I., Niemczyk, R., and Swerev, M., 1988, “Reaction pathways for the formation of polychloro-dibenzodioxins (PCDD) and —dibenzofurans (PCDF) in combustion processes: II. Chlorobenzenes and chlorophenols as precursors in the formation of polychloro-dibenzodioxins and —dibenzofurans in flame chemistry,” Chemosphere, Vol. 17(5), pp. 995-1005.
Bell, J. G., Zhao, X., Uygur, Y., and Thomas, K. M., 2011, “Adsorption of Chloroaromatic Models for Dioxins on Porous Carbons: The Influence of Adsorbate Structure and Surface Functional Groups on Surface Interactions and Adsorption Kinetics,” The Journal of Physical Chemistry C, Vol. 115(6), pp. 2776-2789.
Bernal, J. L., Del Nozal, M. J., Toribio, L., and Brogeras, J., 1992, “Polychlorinated biphenyls analysis in sediments from Castile and Leon reservoirs,” Toxicological and Environmental Chemistry, Vol. 35(3-4),pp. 137-148.
Buekens, A. and Huang, H., 1998, “Comparative Evaluation of Techniques for Controlling the Formation and Emission of Chlorinated Dioxin Furans in Municipal Waste Incineration,” Journal of Hazardous Materials,Vol. 62(1), pp. 1-33.
Buonanno, G., Scungio, M., Stabile, L., and Tirler, W., 2012, “Ultrafine particle emission from incinerators: The role of the fabric filter,” Journal of the Air and Waste Management Association, Vol. 62(1), pp. 103-111.
Cains, P. W., McCausland, L. J., Fernandes, A. R. and Dyke, P., 1997, “Polychlorinated dibenzo-p-dioxins and dibenzofurans formation in incineration: Effects of fly ash and carbon source”, Environmental Science and Technology, Vol. 31(3) , pp. 776-785.
Chevreuil, M., Blanchard, M., Teil, M. J., and Chesterikoff, A., 1998, “Polychlorobiphenyl behaviour in the water/sediment system of the Seine river, France.” Water Research, Vol. 32(4), pp. 1204-1212.
Faroon, O., and Olson, J. N., 2000, “Toxicological profile for polychlorinated biphenyls (PCBs),” Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service.
Griffin, R. D., 1986, “ A new theory of dioxin formation in municipal solid waste combustion,” Chemosphere, Vol. 15(9-12), pp. 1987-1990.
Hutzinger, O., Safe, S., and Zikto, V., 1974, The Chemistry of PCB’s, CRC Press, Boca Raton.
INDRO, 2017, “What is industrial dust collector and baghouse filter bag,” INDRO, Available at：https://www.filterworkshop.com/info/what-is-industrial-dust-collector-and-baghouse-filter-bag-i00277i1.html, 22 November 2017
Jones, A. M., and Harrison, R. M., 2016, “Emission of ultrafine particles from the incineration of municipal solid waste: A review,” Atmospheric Environment, Vol. 140, pp. 519-528.
Kalajzic, T., Bianchi, M., Muntau, H., and Kettrup, A., 1998, “Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in the sediments of an Italian drinking water reservoir,” Chemosphere, Vol 36(7), pp. 1615-1625.
Kim, E. J., Oh, J. E., and Chang, Y. S., 2003, “Effects of forest fire on the level and distribution of PCDD/Fs and PAHs in soil,” Science of The Total Environment, Vol. 311(1-3), No. 1-3, pp. 177-189.
Klamer, J., Laane, R. W. P. M., and Marquenie, J. M., 1991, “Sources and fate of PCBs in the North Sea: a review of available data,” Water Science and Technology, Vol. 24(10), pp. 77-85.
Krishna, S. M., and Krishnamurthy, N., 2018, “Emerging Post Combustion Technologies for Coal Fired Thermal Power Plants,” Power Research, Vol. 14(2), pp. 184-190.
Landers, J. P., and Bunce, N. J., 1991, “The Ah receptor and the mechanism of dioxin toxicity,” The Biochemical journal, Vol. 276 (Pt 2), pp. 273–287.
Lemieux, P. M., Lee, C. W., Ryan, J. V., and Lutes, C. C., 2001, “Bench-scale studies on the simultaneous formation of PCBs and PCDD/Fs from combustion systems,” Waste Management, Vol. 21(5), pp. 419-425.
Lind, T., Hokkinen, J., and Jokiniemi, J. K., 2007, “Fine particle and trace element emissions from waste combustion — Comparison of fluidized bed and grate firing,” Fuel Processing Technology, Vol. 88(7), pp. 737-746.
Luijk, R., D. M. Akkerman, P. Slot, K. Olie, and F. Kapteijn., 1994, “Mechanism of formation of polychlorinated dibenzo-p-dioxins and dibenzofurans in the catalyzed combustion of carbon,” Environmental Science and Technology, Vol. 28(2), pp. 312-321.
McKay, G., 2002, “Dioxin characterisation, formation and minimisation during municipal solid waste (MSW) incineration: review,” Chemical Engineering Journal, Vol 86(3), pp. 343-368.
Metcalfe, J., Stock, M. K., Barron, D. H. Maternal physiology during gestation. In：Knobil E., Neill J, Ewing J. J, Greenwald G.S., Markert, C.L., Pfaff, D.W., 1988, “The Physiology of Reproduction,”New York： Raven Press, pp. 2145-2176.
Milligan, M. S., and Altwicker, E., 1993, “The relationship between de novo synthesis of polychlorinated dibenzo-p-dioxins and dibenzofurans and low-temperature carbon gasification in fly ash,” Environmental Science and Technology, Vol. 27(8), pp. 1595-1601.
Robertson, L. W., and Hansen, L. G. (Eds.)., 2001, PCBs: Recent Advances in Environmental Toxicology and Health Effects, University Press of Kentucky.
Schecter McLachlan M. S., 1997, “A simple model to predict the accumulation of PCDD/Fs in an agricultural food chain,” Chemosphere, Vol. 34(1236-1276), pp. 1263-1276.
Sinkkonen, S., and Paasivirta, J., 2000, “Degradation half-life times of PCDDs, PCDFs and PCBs for environmental fate modeling,” Chemosphere, Vol. 40(9), pp. 943-949.
Stieglitz, L., 1998, “Selected Topics on the De Novo Synthesis of PCDD/PCDF on Fly Ash,” Environmental Engineering Science, Vol. 15(1), pp. 5-18.
Tuppurainen, K., Asikainen, A., Ruokojärvi, P., and Ruuskanen, J., 2003, “Perspectives on the Formation of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans during Municipal Solid Waste (MSW) Incineration and Other Combustion Processes,” Accounts of Chemical Research, Vol. 36(9), pp. 652-658.
US EPA., 1996, “PCBs：Cancer Dose-Response Assessment and Application to Environmental Mixtures” National Center for Environmental Assessment Office of Research and Development U.S. Environmental Protection Agency Washington, DC, EPA-600-P-96-001F.
Van den Berg, M., Birnbaum, L. S., Denison, M., De Vito, M., Farland, W., Feeley, M., Fiedler, H., Hakansson, H., Hanberg, A., Haws, L., Rose, M., Safe, S., Schrenk, D., Tohyama, C., Tritscher, A., Tuomisto, J., Tysklind, M., Walker, N., and Peterson, R. E., 2006, “The 2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-Like Compounds,” Toxicological Sciences, Vol. 93(2), pp. 223-241.
Vogg, H., and Stieglitz, L., 1986, “Thermal behavior of PCDD/PCDF in fly ash from municipal incinerators,” Chemosphere, Vol. 15(9-12), pp. 1373-1378.
Weber, R., Iino, F., Imagawa, T., Takeuchi, M., Sakurai, T., and Sadakata, M., 2001, “Formation of PCDF, PCDD, PCB, and PCN in de novo synthesis from PAH: Mechanistic aspects and correlation to fluidized bed incinerators,” Chemosphere, Vol. 44(6), pp. 1429-1438.
Wiater, I., 2000, “Products, rates, and mechanism of the gas-phase condensation of phenoxy radicals between 500-840 K,” European Journal of Organic Chemistry, Vol. 2000(6), pp. 921–928.
Wiles, C., and Shepherd, P., 1999, Beneficial use and recycling of municipal waste combustion residues-a comprehensive resource document, National Renewable Energy Lab. (NREL), Golden, CO (United States).
WHO, 2016, “Dioxins and their effects on human health,” World Health Organization, Available at：https://www.who.int/news-room/fact-sheets/detail/dioxins-and-their-effects-on-human-health, Accessed 4 October 2016.