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研究生: 林建龍
Lin,Chien-Lung
論文名稱: 廢照明光源處理廠汞流佈之風險評估
Risk Assessment of Mercury Distribution in Waste Lighting Source Treatment Plant
指導教授: 余伍洲
Yu,Wu-chou
學位類別: 碩士
Master
系所名稱: 工學院 - 環境工程與科學系所
Department of Environmental Science and Engineering
畢業學年度: 107
語文別: 中文
論文頁數: 82
中文關鍵詞: 廢照明光源汞流佈作業環境
外文關鍵詞: Waste lighting source, mercury, Mercuric cloth, Work environment
DOI URL: http://doi.org/10.6346/NPUST201900132
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  • 目前生活中含汞產品大部份為燈管,當廢棄照明光源再回收清除處理過程當中未善盡妥善存放,則易造成汞蒸氣逸散於空氣中或污染地下水體,當人們飲用含汞污染水體則可能會造成病變。

    本研究使用物質流分析方式,將回收處理廢照明光源螢光粉及汞蒸氣進行流佈調查,瞭解處理廠內高風險危害處,選定其中具高危害風險3家處理廠,進行廠內汞蒸氣濃度檢測分析之風險評估。廠內處理廢照明光源空氣中逸散量、再生料暫存區、廢棄物暫存區、衍生物產出口、隔離區進出口、衍生物貯存區、己蒸餾螢光粉貯存區、汞及其化合物貯存區、活性碳吸附槽之汞含量為21.60%、2.01%、0.53%、0.43%、0.32%、0.08%、70.09%、4.38%。針對空氣中汞逸散量進行數據風險評估分析結果顯示,廠內各檢測點在非致癌危害指數情境1為0.032-0.212間、情境2為0.053-0.361間、情境3為0.080-0.541間其危害指標均小於1。作業人員配戴呼吸式防毒面罩均可防止作業當中汞蒸氣之隔離並可有效降低汞的危害,並將所有的數值於QR-CODE 上雲端記錄讓進入該作業區域作業人員可得知高風險危害之處。

    廢照明光源逐漸被LED取代近而對人類的危害影響逐漸降低,將有效提升回收率,以達循環經濟將達成國際間汞物質最終使用目的。

    At present, most of the mercury products in life are lamps. When the abandoned illumination lighting source is not properly stored during the recycling process. It is easy to cause mercury vapor to escape in the air or pollute the groundwater. When people drink mercury-contaminated water, it may cause disease.
    This study used substance flow analysis to investigate the flow and distribution of fluorescent powder and mercury vapor of waste lighting sources in recycle treatment to identify places with high risks of hazards in treatment plants. This study selected 3 treatment plants with high risks of hazards to assess the risks of the plants by detecting and analyzing the mercury vapor concentration in the plants. The mercury fugitive emission from treatment of waste lighting sources at the regenerated material temporary storage zone, waste temporary storage zone, derived product outlet, isolation area inlets and outlets, storage zone of derived products, storage zone of distilled fluorescent powder, storage zone of mercury and mercury-containing composites, and active carbon adsorption tank in the plant were 21.60%, 2.01%, 0.53%, 0.43%, 0.32%, 0.08%, 70.09%, and 4.38%, respectively. Risk assessment and analysis results of the fugitive emission of mercury revealed that the noncarcinogenic risk or hazard index in each of the inspection spots in the plant was within 0.032–0.212 in Situation 1, 0.053–0.631 in Situation 2, and 0.080–0.541 in Situation 3; all values of the hazard index was lower than 1. Personnel in the treatment plant can wear a respirator to ward off mercury vapor during the treatment process and effectively reduce the hazard from mercury. Updating all the values through Quick Response Codes on a cloud system can keep personnel entering the operating zone informed of places with high risks of hazards.
    Waste illumination lighting sources are gradually replaced by LED and the impact on humans is gradually reduced. Will effectively improve recycling rate The circular economy will achieve the ultimate use of mercury in international countries.

    摘 要 I
    Abstract II
    誌 謝 IV
    目 錄 V
    表 目 錄 VII
    圖 目 錄 IX
    第一章 前言 1
    1.1研究緣起 1
    1.2研究動機 2
    1.3研究目的 2
    第二章 文獻回顧 4
    2.1汞基本介紹 4
    2.1.1汞基本特性 4
    2.1.2汞基本危害 6
    2.1.3汞的應用 10
    2.2廢照明光源概述 11
    2.2.1廢照明光源結構處理流程 13
    2.2.2廢照明光源質量平衡流程 14
    2.2.3廢照明光源回收現況 18
    2.2.4廢照明光源回收沿革 19
    2.2.5廢照明光源處理流程、設備 20
    2.3物質流分析理論基礎探討 26
    2.3.1物質流分析演進 26
    2.3.2物質流分析定義 27
    2.3.3物質流分析類型 30
    2.4二維條碼 QR Code之基本資訊 32
    2.4.1 QR Code 電子票務與生產資訊應用 34
    第三章 材料與方法 35
    3.1針對國內廢照明光源處理廠內汞蒸氣採樣點規劃 35
    3.1.1處理業者之擇定 35
    3.1.2採樣地點及方法擇定 37
    3.2物質流分析流程及步驟 41
    3.3廢照明光源現場作業環境危害風險之評估 43
    3.3.1風險評估流程 44
    3.3.2非致癌指標之風險評估 45
    第四章 結果與討論 49
    4.1處理含汞廢照明光源廠之汞流佈數據分析 49
    4.1.1數據收集盤查 49
    4.1.2模擬及物質平衡 58
    4.2廢照明光源處理廠含汞作業環境之風險分析 67
    4.2.1非致癌指標的風險分析 67
    4.3廢照明光源處理廠之數位化自主管理檢查表 70
    第五章 結論與建議 73
    5.1結論 73
    5.2建議 74
    參考文獻 76
    作者介紹 82

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