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研究生: 洪挺鈞
Ting-Chun Hung
論文名稱: Ce3+,Tb3+共摻雜對LiSrPO4螢光粉之微結構與光學特性的影響之研究
Study on Microstructure and Photoluminescence Properties of LiSrPO4 Phosphor Co-doped with Ce3+, Tb3+
指導教授: 楊茹媛
Ru-Yuan Yang
學位類別: 碩士
Master
系所名稱: 工學院 - 材料工程研究所
Graduate Institute of Materials Engineering
畢業學年度: 109
語文別: 中文
論文頁數: 44
中文關鍵詞: 螢光粉磷酸鋰鍶固態反應法
外文關鍵詞: phosphor, lithium strontium phosphate, solid state reaction method
DOI URL: http://doi.org/10.6346/NPUST202100018
相關次數: 點閱:58下載:0
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  • 論文摘要:
    Tb3+,Ce3+當作活化劑發光中心之為結構與發光特性,本研究參考畢業學長實驗過去研究所得之Tb3+之最佳摻雜濃度,以固定活化劑Tb3+濃度,改變增感劑Ce3+摻雜濃度進行共摻雜實驗,探討Ce3+摻雜濃度與燒結溫度對(LiSrPO4: Ce3+, Tb3+)之微結構與光學性質。
    本研究使用X-光粉末繞射儀(X-ray Diffraction,XRD)、掃描式電子
    顯微鏡(Scanning Electron Microscope,SEM)與國家奈米實驗室的光致發光光譜儀(Photoluminescence Spectrum,PL)其微結構與光學性質。LiSr1-x-yPO4:xTb3+,yCe3+,其中活化劑Tb3+濃度固定值為Tb3+ = 9mol%,增感劑Ce3+摻雜量濃度變化為(y = 0.01, 0.03, 0.05, 0.07, 0.09 mol%) ,當燒結溫度為1200℃,其XRD分析皆為純相,從PL分析,共摻雜可以有效提升能量吸收,從CIE圖分析顯示LiSr1-x-yPO4:yCe3+, xTb3+螢光粉Ce3+摻雜濃度增加而逐漸由綠光轉變為藍光,可作為可調式螢光粉之候選。

    Abstract of the paper:
    The main purpose of this article is to investigate the microstructure and
    luminescence characteristics of lithium strontium phosphate co-doped rare
    earth ions of Tb3+ and Ce3+ as the luminescence center of the activator. This study refers to the optimal doping concentration of Tb3+ obtained from the experimental study of graduates so that we fixed the concentration of activator Tb3+, and changed the doping concentration of sensitizer Ce3+ to conduct co-doping experiments to explore the effect of Ce3+ doping concentration and sintering temperature on the microstructure and optical properties of LiSrPO4: Tb3+, Ce3+.
    This study used X-ray powder diffraction (X-ray Diffraction, XRD), scanning electron microscope (Scanning Electron Microscope, SEM), photoluminescence spectrometer (PL) to analyzed the microstructure and optical properties of LiSr1-x-yPO4: yCe3+, xTb3+. LiSr1-x-yPO4: yCe3+, xTb3+ with the fixed concentration value of the activator Tb3+ is Tb3+= 9mol%, and the sensitizer doping concentration of Ce3+ changes to (y=0.01, 0.03, 0.05, 0.07, 0.09 mol%).
    When sintering The temperature is 1200℃, and the XRD analysis is pure phase. From PL analysis, the energy absorption for phosphors LiSrPO4 with co-doping rare earth ions of Tb3+ and Ce3+ can effectively be increased. Analysis from CIE diagram shows that LiSr1-x-yPO4: yCe3+, xTb3+ phosphors gradually change from green light to blue light due to the increase of Ce3+ doping concentration. The LiSr1-x-yPO4: yCe3+, xTb3+can be a candidate for tunable phosphor.

    目錄

    摘要 Ⅰ
    ABSTRACT Ⅱ
    謝誌 Ⅳ
    目錄 V
    表目錄 Ⅶ
    圖目錄 VIII
    第1章緒論 1
    1.1前言 1
    1.2文獻回顧 2
    1.3研究動機與目的 3
    第2章基礎理論 6
    2.1 螢光材料簡介 6
    2.2 螢光體的發光原理 6
    2.3 發光機制簡介 6
    2.4 螢光粉組成與選擇 7
    2.4.1主體晶格(Host lattice)的選擇 7
    2.4.2活化劑(Activator)的選擇 7
    2.4.3增感劑 (sensitizer) …..8
    2.5 影響發光行為與效率的因素 ..9
    2.5.1濃度消淬效應(Concentration quenching effect) …..9
    2.5.2毒劑效應(Poisoning effect) 10
    2.5.3熱消淬效應(Thermal quenching effect) 10
    2.6 CIE色度座標 10
    第3章實驗步驟與分析方法 18
    3.1 實驗藥品 18
    3.2 實驗方法與步驟 18
    3.3 量測系統與特性分析 19

    3.3.1 X-ray繞射儀(X-ray diffraction) 19
    3.3.2掃描式墊子顯微鏡(Scanning electron microscope) 20
    3.3.3螢光光譜儀(Photoluminescence) 21
    第4章結果與討論 26
    4.1 XRD結構分析 26
    4.2 SEM表面型態分析 26
    4.3 PL激發放射光譜分析及CIE座標圖 28
    4.3.1濃度淬減效應 29
    4.3.2光至發光衰減現象 29
    第5章結論 42
    參考文獻 43

    參考文獻

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