The charge densities of carbon of cyclopropane ring in the cyclopropylarenes were calculated by means of semi-empirical molecular orbtial methods (AMI, MNDO, PM3). Correlations between the charge densities of carbon, Hammell σ, σ^+, σ^- constants and substituent chemical shifts(SCS) from ^(13)C NMR studies were made. The charge densities of C_σ C_7 (from AMI, MNDO) can well be correlated with Hammell σ, σ^- as well as SCS. The presence of halogens on C_β resulted in higher field effect and the changing of substituents did not affect the consistency of the charge densities. In general, methods of AMI and MNDO can be applied to the prediction of the chemical shifts of carbon on the cyclopropyl series.