This study presents a ZnO nanostructures on Si(100) substrate by liquid phase deposition. We decide the substrate’s position in the beaker, with the seed layer or not, and improve the precesss of seed layer, to get a successful way to grow the ZnO nanostructures with high direction. And especially, we obtain several different kind of shape of ZnO nanostructures, some of them have the value of study more to get high arrangement ZnO nanostructures by control steadily. More importantly, this study introduction this fabrication into our lab, with low cost, simple, and suit much kinds of substrates. We believe that this study and the successful way of grow high arrangement ZnO nanostructures can improve our lab for multiplex research.