以MPCVD成核技術成長奈米接枝碳管簇輔助有機太陽能電池之研究

A Study of Enhancing Organic Solar Cell by CNTs Grown Using Modified Nucleation in MPCVD

林呈憲(Cheng- Hsien Lin)

指導教授 ： 林啟瑞 ； 蘇春熺

國立臺北科技大學/機電學院/機電整合研究所/碩士(2008年)

https://doi.org/10.6841/NTUT.2008.00238

摘要

本研究主要應用微波電漿化學輔助氣相沈積、沈浸法及溶膠凝膠法調製而成的溶液來成長奈米接枝碳管並應用於有機太陽能電池，並於一次成長之奈米碳管上成長二次接枝碳管之方法，藉此技術用以提高碳管之比表面積，而此立體空間之奈米結構，預期可成長出媲美甚至超越奈米碳角的比表面積特性。同時，亦利用不同之碳管形貌及不同觸媒層作為有機太陽能電池之導電層，進而從中挑選出具有最佳電子電洞傳導率之碳管形貌。
此外，本研究的應用重點即在於製作一有機/奈米碳管接枝材料太陽能電池，其中半導體型態的奈米碳管接枝材料的加入，目的是在於利用其一維結構之電子傳輸特性優良，使有機太陽電池光電轉換效率提升，已有2.5％的光電轉換效率之提升。

關鍵字

奈米碳管 ； 有機太陽能電池 ； TiN膜 ； CNFNc ； 微波電漿化學輔助氣相沈積

並列摘要

This research is based on MPCVD to grow a brand new type of CNTs. For the outstanding electric conductivity of CNTs, it was used to be put into a self-made organic solar cell in order to increase the light-electric efficiency. By using the submergence technique, the sol-gel is able to attach to the first-time grown CNTS and form a thin layer as a pretreatment for the second-time grown CNTs. Moreover, by using this technique, a brand new type of CNTs is able to be formed which can be compared with carbon nanohorns. Based on the research, three-dimensional structure CNTs have a better electrical conductivity than the first-time grown CNTs.
Furthermore, by using MPCVD different types of CNTs can be grown, then using a different catalyzer and applying these onto organic solar their effects can be discussed; by measuring the I-V curve to acknowledge that the brached CNTs can offer a higher electric conductivity.

From the result of light-electric efficiency, it is clear that the organic solar cell with branched CNTs has a higher light-electric efficiency than first-time grown CNTs, about 2.956% higher.

並列關鍵字

CNTs ； organic solar cell ； Tin ； CNFNc ； MPCVD

參考文獻

[3] 洪昭南, 徐逸明, 王宏達，「奈米碳管結構及特性簡介」，奈米級碳管之研發專刊，化工，第49卷第1期, 2002.

[18] 廖國材，以新穎之微波電漿束化學氣相沈積法進行奈米碳管及鑽石膜之圖案成長，碩士論文，國立台北科技大學製造科技研究所，台北，2006. 第93頁

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