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研究生： 游聲宇
Yu, Sheng-Yu
論文名稱： 探討NCM陰極材料在鋰離子電池之反應機制
Mechanistic Insight of NCM Cathode in Lithium Ion Batteries
指導教授： 陳貴賢
Chen, Kuei-Hsien
林麗瓊
Chen, Li-Chyong
吳恆良
Wu, Heng-Liang
學位類別： 碩士
Master
系所名稱： 化學系
Department of Chemistry
論文出版年： 2020
畢業學年度： 108
語文別： 中文
論文頁數： 104
中文關鍵詞： 鋰離子電池 、鎳鈷錳三元材料 、臨場X-ray繞射 、臨場快速X-ray吸收 、奈米探針 、奈米繞射
英文關鍵詞： Lithium ion battery, NCM, In-situ XRD, In-situ q-XAS, Nanoprobe, Nanodiffraction
DOI URL： http://doi.org/10.6345/NTNU202000923
論文種類： 學術論文
相關次數： 點閱：99  下載：0 
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    • 謝辭 I 摘要 II Abstract III 目次 V 表次 VIII 圖次 IX 第一章、 緒論 1 1.1 前言 1 1.2鋰離子電池發展 2 1.3鋰離子電池機制 4 1.4鋰離子電池優缺點 5 1.5鋰離子正極材料介紹 6 1.5.1 LiCoO2 7 1.5.2 LiNiO2 8 1.5.3 LiMnO2 10 1.5.4 Li[Ni1-x-yCoxMny]O2三元材料 (NCM) 11 1.5.5正極材料之比較 14 1.6文獻回顧 14 1.7研究動機 20 第二章、實驗方法 21 2.1實驗藥品、器材和儀器 21 2.1.1 實驗藥品 21 2.1.2 實驗器材 22 2.1.3 實驗儀器 23 2.2 CR2032鈕扣型電池 24 2.2.1電極製備 24 2.2.2電解液配製 24 2.2.3電池組裝 25 2.3臨場X-ray繞射實驗 (D2 advanced) 26 2.3.1電極製備 26 2.3.2電池組裝 26 2.3.3實驗架設 27 2.4臨場X-ray吸收實驗(NSRRC) 28 2.4.1電池組裝 28 2.4.2實驗架設 29 2.5分析方法與儀器介紹 30 2.5.1循環伏安法 30 2.5.2 X-ray繞射儀 30 2.5.3 X-ray吸收光譜 32 2.5.4 X-ray 奈米探針實驗 (TPS-23A) 33 2.5.5 X-ray奈米繞射實驗 (TPS-21A) 34 2.5.6電感耦合等離子體-質譜法(Inductively coupled plasma-Mass Spectrometry) 35 第三章、結果與討論 37 3.1三元材料電化學表現 37 3.1.1不同鎳含量材料之循環伏安法 37 3.1.2 三元材料在充放電過程的穩定性 39 3.2臨場X-ray繞射儀 41 3.2.1 NCM523臨場X-ray繞射 42 3.2.2 NCM811臨場X-ray繞射 48 3.2.3鋰離子嵌出與結構之關係 53 3.2.4結構變化與動力學&熱力學之關係 57 3.2.5比較先前鋰離子電池之陰極材料 60 3.3臨場X-ray快速吸收 60 3.3.1 NCM523臨場X-ray快速吸收Near-Edge Spectroscopy 61 3.3.2 NCM811臨場X-ray快速吸收Near-Edge Spectroscopy 69 3.3.3 NCM523臨場X-ray快速吸收EXAFS 78 3.3.4 NCM811臨場X-ray快速吸收EXAFS 82 3.4 NCM不同電位之XAS-mapping圖 86 3.5 NCM不同電位之XRD與XRF-mapping圖 88 3.6 過渡金屬溶出對電化學表現的影響 96 第四章、結論 99 參考文獻 101

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