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  • 學位論文

由二級銨離子延伸新型分子開關之研究

Modifying sec-Ammonium Based [2]Rotaxanes to New Molecular Switches

指導教授 : 邱勝賢
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摘要


以二級銨離子為基礎的車輪烷可以透過外加酸鹼的刺激,來控制其分子開關的行為,在超分子化學上有很大的應用潛力,在文獻上亦已有不少報導。我們希望能夠針對具二級銨官能基的車輪烷分子進行修飾,以便發展出更具多樣性應用的新型分子開關系統。

關鍵字

超分子化學 車輪烷

並列摘要


The pH-controllable molecular rotaxanes based on dialkylammonium ions have been proven to be useful materials in different fields. By modifying the dialkylammonium ion to a new recognition motif after the assembly of the rotaxanes, new molecular switches with versatile function may be developed with ease.

並列關鍵字

Supramolecular Chemistry Rotaxane

參考文獻


2. (a) Nicolau, K. C. Classics in Total Synthesis: Targets, Strategies, Methods. Wiley, 1996 (b) Nicolau, K. C. Classics in Total Synthesis II: More Targets, Strategies, Methods. Wiley, 2003
6. Quiñonero, D.; Garau, C.; Rotger, C.; Frontera, A.; Ballester, P.; Costa, A.; Deyà, P. M. Angew. Chem. Int. Ed. 2002, 41, 3389-3392
12. Lehn, J. M. Supramolecular Chemistry, VCH: Weinhein, 1995
18. Lehn, J. M. Angew. Chem. Int. Ed. Engl. 1988, 27, 89-112
19. Cram, D. J. Angew. Int. Ed. Engl. 1988, 27, 1009-1020

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