- 學位論文
在可見光介導下，以脫碳方式，催化烯烴/炔烴/丙烯基與異氰化合物合成醯胺鍵。
Visible Light Mediated Amidation of Alkenyl / Alkynyl /Allyl Group with Isocyanides via Carbon Deletion
並列摘要
In this project, we have developed a novel, efficient and mild condition for amide bond construction from phenyl acetylene/styrene/allyl benzene and isocyanide in the presence of TBHP/TBAI as an oxidant under light condition. This protocol might be an alternative procedure for the amidation under the metal free via radical pathway from isocyanide with step down reaction. The notable features of this protocol are carbon deletion, broad substrate scope, mild condition, visible light, and metal free. Moreover, this is a new tactics for the synthesis of amide bond from Alkyne/Alkene/Allyl group with Isocyanides via carbon deletion strategy in the presence of visible light.
參考文獻
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延伸閱讀
- Bhaskar, P. Y. (2021). 金金屬催化炔類與烯丙醯胺類化合物以合成具高官能性分子 [doctoral dissertation, National Tsing Hua University]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0016-0209202114084485
- Tseng, C. C. (2014). 有機金屬金催化縮醛與烯烴環化加成反應及銅催化N-羥胺需氧氧化反應之研究 [master's thesis, National Tsing Hua University]. Airiti Library. https://doi.org/10.6843/NTHU.2014.00239
- 陳建銘（2014）。金、銅催化未活化累積二烯烴分子與苯羥胺於氧氣下行[4 + 2] 環加成反應〔碩士論文，國立清華大學〕。華藝線上圖書館。https://doi.org/10.6843/NTHU.2014.00240
- 林廷華（2015）。雙鉬金屬五重鍵與炔之[2+2+2]環化加成反應及與有機氯化物之碳-氯鍵活化反應研究〔碩士論文，國立清華大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0016-0312201510260533
- Sundar, G. S. (2018). Transition Metal Catalyzed Functionalization of Alkynes: An Access to divergent Molecular Framework [doctoral dissertation, National Tsing Hua University]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0016-1803201914453723