This thesis focuses on utilizing Volatility Index (VIX) of Chicago Board Options Exchange (CBOE) as an indicator of market timing in investing the emerging BRICS stock markets (Brazil, Russia, India, China and South Africa). The goals of this study are to strengthen the market timing ability of VIX index, construct investment opportunities that buy at the bottom, sell at the top of the market. Our data were obtained from CBOE and Taiwan Economic Journal (TEJ) database for the period of January 1990 to December 2013. In this study, we considered the moving feature of stock index which is quick fall and slow rise and the deferred effect of stock indexes and VIX index in different stock markets. Vector auto regression (VAR) model was used to find the optimal time lag between BRICS stock indexes and VIX index. The empirical results revealed almost all of the investment opportunities got positive returns, suggested VIX can serve as a useful market timing indicator in emerging BRICS stock markets. We found VIX index has five major features: useful in market timing, powerful in getting stable and high profits, effective at reducing investment risk, international eligibility and convenient for getting data. It was concluded that our investment opportunities which utilized VIX index as market timing indicator can not only significantly reduce risk but also improve investing performance.