Title

烯基自由基與矽基酮的連繼性環化反應研究

Translated Titles

The Study of Tandem Radical Cyclization of Vinyl Radical with Acylsilanes

DOI

10.6342/NTU.2007.00632

Authors

張怡萱

Key Words

矽基酮 ; 自由基 ; 連繼性 ; 環化 ; acylsilane ; radical ; tandem ; cyclization

PublicationName

臺灣大學化學研究所學位論文

Volume or Term/Year and Month of Publication

2007年

Academic Degree Category

碩士

Advisor

蔡蘊明

Content Language

繁體中文

Chinese Abstract

本篇論文是利用末端帶有烯基碘的矽基酮為自由基的起始物,在主碳鏈上引入末端含不飽和鍵的支鏈,希望達到連繼性的環化反應。此一環化體系的主體用矽基酮這個官能基,環化後的氧自由基透過Brook重排避免開環以達環化。以烯基碘產生烯基自由基,與矽基酮環化及重排之後得到的是一個烯基自由基,因此我們的挑選最先是採用末端炔矽基,之後也改變為不同的不飽合鍵,以利於達成連繼性環化反應的雙環產生。

Topic Category 基礎與應用科學 > 化學
理學院 > 化學研究所
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