Organochlorine pesticides have stable chemical structure, high toxicity and bioaccumulation. Consequently, it is necessary that they be monitored in soil. In this study, headspace solid-phase dynamic extraction (HS-SPDE) was applied to examine thirteen organochlorine pesticides in water and soils. The extraction method proved to be a rapid, solvent free and no clean-up procedures technology. The detection limit of HS-SPDE for OCPs in water is 0.001-0.05μg/L and conformed to the European Community standard in which the sum of pesticides must lower than 0.5μg/L. The detection limit of HS-SPDE for OCPs in soil is 0.15-2.91μg/kg. On the whole, HS-SPDE was a good method for the routine analysis of OCPs in water and soil.