- 期刊
- OpenAccess
使用螯合樹脂離子交換法濃縮海水中銅離子之研究
Pre-Concentration of Dissolved Copper Ions in Sea Water Using Chelating Ion-Exchange Technique
並列摘要
The possibility of using chelating ion-exchange technique to concentrate copper ions from sea water prior to the detection with atomic absorption spectrophotometry was monitored by means of a series of standard test. The effects of pH, flow rate and ionic strength applied in various types of elution were carefully examined in order to obtain suitable conditions for the sea water spiking experiments. Results show that the method can be specific for the determination of. copper in sea water at ppb levels and that the method have several advantages in comparison with other solvent extraction procedures in terms of convenience, rapidity and less possible contamination introduced through the addition of chemical reagents. The copper detected by the suggested method covers complete species of ions and inorganic complexes but for sea water analysis, the real concentration could be under-estimated if some organic substance-chelated copper species exist. However, the ease of handling this pre-concentration procedure allows more samples to be analyzed hence it is of great value to oceanographic and pollution studies.
並列關鍵字
無資料延伸閱讀
- 鍾仕偉、白書禎、陳秋妏、董正釱、歐錫祺（1997）。海水中微量金屬元素濃縮問題的探討第二部分：以Chelex-100鉗合樹脂－石墨爐原子吸收光譜法測定海水中溶解性鎘銅鎳鋅鈷元素。化學，55(1)，29-36。https://doi.org/10.6623/chem.1997004
- 洪東巽（2007）。應用固相微萃取法配合蟹殼與幾丁聚醣來分析及處理水中有機氯殺蟲劑〔碩士論文，淡江大學〕。華藝線上圖書館。https://doi.org/10.6846/TKU.2007.00291
- 鍾仕偉、白書禎、陳秋妏、董正釱、歐錫祺（1997）。Chelex-100鉗合樹脂濃縮海水中微量金屬元素之效率預測。化學，55(3)，25-39。https://doi.org/10.6623/chem.1997029
- Sadrolhosseini, A. R., Rashid, S. A., Zakaria, A., & Shameli, K. (2016). Green Fabrication of Copper Nanoparticles Dispersed in Walnut Oil Using Laser Ablation Technique. Journal of Nanomaterials, 2016(), 656-662-266. https://doi.org/10.1155/2016/8069685
- 陳育群（2007）。The Study of the Cuprous Copper on Copper Deposition by Electrochemical Techniques〔碩士論文，中原大學〕。華藝線上圖書館。https://doi.org/10.6840/cycu200700754