This article discusses with caustic of different concentrations to process the density to the Lyocell fiber dyeing adsorbability influence. First passes through the Lyocell fiber with 5, 10, 15, 20% alkali processing, then carries on the adsorption by three kind of different structures reactivity dye, then observes its adsorption behavior if it fits, and conforms to what kind of adsorption equation. Knew by the experimental result that, the Lyocell fiber adsorption behavior can have the change along with the caustic concentrations increase. But when with the caustic concentrations 5%-15% processing the adsorbed by the fiber for is highest to the fiber, the dye adsorption behavior is not the same.