Carbon dioxide capture and geosequestration is one of key greenhouse gas abatement technologies in Taiwan. To assist and accelerate the pilot-scale and large-scale demonstrations, ITRI has establish core techniques for site evaluation, monitoring, and numerical transport simulation for geosequestration in Taiwan. We have developed joint geophysical imaging and shear-wave splitting techniques to integrate seismic reflection, microseismic and magneto-telluric data that can reveal more detailed insights of underground geological structures in potential injection site. Numerical transport simulation technique is also developed to predict the behavior of carbon dioxide plume during and after large-scale injection. By implement these core technologies, we have constructed a framework for site evaluation and monitoring, which will provide a good basis for site planning and monitoring strategy.