天胡荽精油成分之研究

Components of Essential Oil from Hydrocotyle Sibthorpioides Lam

郭文隆(Wen-Lung Kuo) ； 周育寬(Yu-Kwan Chou) ； 謝博進(Bor-Jinn Shieh)

《崇仁學報》 3期 (2009/12) Pp. 1-12

https://doi.org/10.6485/JCJJCNHSM.200912.0001

摘要

本研究旨在探討由天胡荽抽取出之精油成分，並比較在抽取過程中所萃取得到的精油成分及收油率之差異性。天胡荽中性精油經萃取得到的萃取液粗分成含碳氫化合物（利用正己烷萃取得到）和含氧化合物（利用乙醚萃取得到）兩大部分；所占全精油的比率，含碳氫部分爲28.32%，含氧部分71.64%。在利用管柱細分後加以純化，將純化物的物質、含碳氫部分以及含氧部分利用氣相層析儀－火燄離子偵測器(GC-FID)、氣相層析－質譜儀(GC-MS)等儀器鑑定其化學成分，於含碳氫化合物中確認了15種精油成份，且於含氧化合物中確認了19種精油成份，共計得到34種精油成份。其中α-Santalene, 2,5-Dimethoxy-p-cymene, Caryophyllene oxide, Hexahydrofarnesylacetone, β-Elemene, 3-(4,8,12-Trimethyltridecyl) furan, 6-Isopropenyl-4, 8a-dimethyl-1,2,3,5,6,7,8, 8a-octahydro-naphthalen-2-ol爲首次從天胡荽中分離而得到。

關鍵字

天胡荽 ； 精油 ； 液相管柱色層分析 ； 氣相層析儀－火燄離子偵測器 ； 氣相層析－質譜儀

並列摘要

The aim of this study was to investigate the components of essential oil from Hydrocotyle sibthorpioides Lam. The neutral essential oil fraction was separated by column chromatography and thirty-four essential oil compounds were extracted from Hydrocotyle sibthorpioides Lam., which were identified by comparison of GC retention times and GC/MS spectroscopic analysis. In addition, the fifteen compounds from carbon-hydrgened fraction (28.32%) and the nineteen compounds from oxygenated fraction (71.64%) have been isolated, respectively. Seven compounds, including α-santalene, 2,5-dimethoxy-p-cymene, caryophyllene oxide, hexahydrofarnesylacetone, β-elemene, 3-(4,8,12-trimethyltridecyl)furan, and 6-isopropenyl-4,8a-dimethyl-1,2,3,5,6, 7,8,8a-octahydronaphthal-en-2-ol were isolated from Hydrocotyle sibthorpioides Lam. for the first time.

並列關鍵字

Hydrocotyle sibthorpioides Lam ； Essential oil ； Liquid chromatography ； GC-FID ； GC-MS