Due to the changes of commercial competition, science and technology, and consumptive pattern, the traditional way of marketing is no longer satisfied by consumersand the economy developing process has been changed to "Experience Economy." Experience marketing provides customers with various consumption experiences that can really influencial their sense and emotion. It provides good opportunities to establish long-term relationships with customers. This study examines the relationship between experiential modules (sense experience, feel experience, think experience, act experience, and relate experience), perceived value, and purchase intentions. For quantitative analysis, it takes purposive sampling at Starbucks coffee shops in Taiwan. Total 300 questionnaires were collected, and 58 were removed from the sample because of incomplete answers. The valid samples were 242(80.6%). The findings are as follows: 1. Experiential marketing was positive related with perceived value. 2. Experiential marketing was positive related with purchase intentions. 3. Perceived value was positive related with purchase intentions. Besides, some implications of these findings for business organizations and scholars are discussed.