This paper reports a case study that involved studying and simulating the potential for photovoltaic (PV) electricity generation at Hojing Elementary School by using the RETScreen model. The electricity generation simulated by the existing 3.67-kW PV power system for 2011 was 5,428 kWh, which was very similar to the actual electricity generation for that same year (5,427.7 kWh). However, inaccuracies in the simulations over 8 months were greater than 10%. Based on the total rooftop area available for installing PV panels, a capacity of 355.12 kW and a total electricity yield of 174% of the school’s electricity demand can be achieved. The validation of the RETScreen model in this study indicated that the model is able to accurately simulate the yearly technical potential of proposed PV projects. However, the reliability of the model to analyze the potential monthly electricity generation of the proposed project needs to be enhanced.