含1,2,4,5-四(磷酸亞甲基)苯配子配位聚合物之自組裝合成、結構與性質探討

Self-assembly, Structures and Properties of 1,2,4,5-Tetrakis(methylenephosphonic acid) benzene Containing Coordination Polymers

李宜峰(Yi-Feng Li)

指導教授 ： 曾添文 ； 呂光烈

國立臺北科技大學/工程學院/化學工程研究所/碩士(2011年)

https://doi.org/10.6841/NTUT.2011.00551

摘要

本文研究為四磷酸基的有機配子1,2,4,5-tetrakis(methylenephosphonic acid) benzene (H8tmpb)與過渡金屬離子 (MnII、CoII、NiII)及鹼土族金屬離子(MgII、CaII、BaII)，在調控的酸鹼及溫度環境下，進行自組裝合成，製備有機-無機金屬之配位聚合物。

第一部分，以過渡金屬離子(MnII、CoII、NiII)與H8tmpb利用水熱法與溶劑熱法反應，在高溫及高pH值條件，得到兩個等結構的三維配位聚合物{[Co2(H4tmpb)(H2O)4]

關鍵字

配位聚合物、磷酸基配位子、自組裝

並列摘要

In this thesis, a tetra-phosphonate acid ligand, 1,2,4,5-tetrakis (methylenephosphonic acid)benzene (H8tmpb), was used to react with various transition-metal ions (MnII, CoII and NiII), and alkaline earth ions (MgII, CaII and BaII), under hydrothermal process in different pH conditions. From these reactions, several coordination polymers were successfully obtained and characterized.

In the first part of this report, H8tmpb was reacted with three transition-metal ions (MnII, CoII and NiII) to form four coordination polymers {[Co2(H4tmpb)(H2O)4]

並列關鍵字

coordination polymer, phosphonate ligand, self-assembly

參考文獻

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