In the era of electronic products change with each passing day, the periods of developing electronic products and life cycles of electronic products are shortened dramatically. In addition, along with the arousal of environmental consciousness, green products, including Print Circuit Board, have drawn people’s close attention worldwide. Japan takes environmental consciousness seriously, especially in communication and electronic industries. Hence PCB manufacturers have faced critical challenge. Ordinarily, PCB contains haloid flame-retardant, which would produce carcinogenic gas such as dioxin and benzofuran if inflamed in impropriate temperature. This toxic gas could cause air pollution and endanger human, then affect environmental protection indirectly. Therefore, the paper proposed here analyses effects of diverse flame-retardants, fill-ers and additives and their characteristics. The experiment shows that the amount of inorganic phosphorus in inorganic filler affects the pyrolysis temperature of that specific material. We also prove that more oxygen inorganic filler contains the better for oxide could increase insulation performance. And this will result to better dimensional stability, rigidity, workability, flame-retardant and electric performance. For this reason, halogen-free laminates could totally replace ordinary laminates in performance or process and thereby convert PCB into environmental electronic products.