This study uses the three-year survey data of「Taiwan Assessment of Student Achievement」in 2009、2010 and 2011 to explore the impact of parental marital status on children’s mathematic performance. I use mathematic scores as a child’s educational performance, because that mathematic scores have been considered to have a positive relationship with future human capital. In additional, the main explanatory variable is binary variable for indicating family’s marital status, which is divided into “divorce” and “separation”with base group of intact family. Using the ordinary least squares method,we found that the math scores of children whose parents were divorced were significantly lower than those of children whose parents lived in intact family. However, due to the incompleteness of the data, there are still many family background factors that cannot be controlled in the model, which is the limitation of this study.