In recent years, the key technologies of wireless sensor network have been rapidly developing. As the wireless sensing devices become cheaper and smaller, these miniaturized nodes offer the opportunity for the electronic sensor to many different applications. The practical applications of wireless sensor network require high-performance, low power consumption, more reliable and more prolonged lifetime deployments for potentially a very large number of wireless sensor and actuator nodes. In this paper, the sensor nodes with energy harvesting are studied and developed to reach the goal having the independent energy, and to effectively extend the life cycle of sensor nodes and network. The energy harvesting circuit with MPPT function is designed to capture and transform the solar energy to charge the rechargeable battery to provide the power of wireless sensor nodes and extend the lifetime of battery. This harvesting circuit is implemented by applying LT362HV IC as system core to achieve the catch and conversion of solar energy. The main objective of this study is to optimize the energy efficiency of wireless sensors and life cycle, and furthermore to enhance and extend the application reliability and practicability of wireless sensor network.