The ZnO nanostructures were synthesized on flexible soft substrate using chemical deposition methods. We applied the epitaxial growth to produce ZnO nanorods and assembled the nanogenerator with the nanorods. ZnO nanostructures were grown using liquid solution epitaxial method. In liquid epitaxial, effects of growth temperatures, growth times, and growth concentrations on the morphology and characteristics of ZnO nanorods were discussed. The results showed when the temperatures increased, the diameters of the nanowires increased. The XRD results found that the ZnO nanowires had monocrystalline (0002) structure. The ZnO nanostructures had good peak values in ultraviolet emission and blue emission. Finally, making on top of electrode to fabricate nanogenerator with ZnO nanorods and measured micro-current driven by ultrasonic waves, and measuring its voltage and current characteristics. To explore how different deflections of the electromechanical characteristics change with the state of bending in the substrate.