The change of mankind's life with the development of the technology and becomes more convenience and comfortable. It also makes us to need more energy.So It is very important to develop the new energy. The solar energy is the best choice. The Titania based dye sensitized solar cells invented in 1991 by the Swiss Physicist, Michael Grätzel.We prepare the TiO2 film with Sol-Gel and doctor blade. .TPP(tetraphenylporphine) and Laser dye are used as to dye respectively. R610 Chloride cell. and Zn-TPP cell show the best photo-to-electron power conversion efficiency,η.in TPP cells and laser dye cells, respectively.