Food, healthy food and even herbs are rich in variety of carbohydrates and some of these carbohydrates may have specific functionalities. A reliable method to qualitative and quantitative analysis of various carbohydrates is required. For this purpose, this study using capillary electrophoresis successfully established three fast, stable and cheap methods of analysis, including PMP (1-phenyl-3-methyl-5-pyrazolone) derivative, APTS (8-aminopyrene-1,3,6-trisulfonate) derivative, and indirect methods. Through combinational usage of these three methods, at least 22 kinds of carbohydrates can be analyzed. This established methodology can be applied to routinelyinspectcarbohydrates in foods and products.