Purpose: This study is aimed to explore the influence of the leading way made by table-tennis coach on the sport psychological skills of athletes. Method: The research sample was taken the male and female athletes from the open group of 2013 National College Cup of Table-Tennis Competition as the study objects. Upon the competition date, a total of 120 questionnaires were distributed with 105 returned copies of them which made an effective rate by 87.5%. Result: The leading way of coach has a positive correlation with the psychological skills of athletes. The leading way of coach has made a significant influence on the motivation and teachable nature of psychological skills in athletes, particularly having a largest difference of teachable nature. Conclusion: The more coach leading has made a better motivation and teachable nature of the athletes. And, the leading way of coach can make an influence on the motivation and teachable nature of psychological skills in athletes. It suggests the coach and relevant units should diagnose and inspect again the training program of psychological skills for athletes in order to adjust the leading way of coach.