In this study, polyvinyl alcohol (PVA) was used as raw material to change the ratio of polysaccharide alcohol to water, and the composite membrane for air filtration was prepared by electrospinning. The effect of changing the ratio of polysaccharide alcohol on the cold sensation of composite film was discussed. The fiber surface and fiber fineness were observed by electron microscopy. The results show that when the total proportion of polysaccharide alcohols reaches 20%, the thermal conductivity and thermal dissipation value will be higher. The experiment shows that the electrospun fibers added with polysaccharide alcohols have the effect of cooling the whole composite film.