Silicone rubber is an accurate rapid tooling material based on dimensional stability. To enhance the efficiency of making the silicone rubber mold, accurately measuring the solidification time is an important issue. This study demonstrated a non-destructive measurement system to determine the solidification time of silicone rubber. The criterion for determining the solidification time of silicone rubber was proposed according to the changes both in the transmitted power and temperature obtained. The predicted equation for predicting the solidification time of silicone rubber mold was proposed. The applicability of the solidification time using the predicted equation was investigated and compared with manual measurement. The relative error of the predicted equation was also investigated. The entire solidification processes of silicone rubber mold were finally demonstrated.