In response to the development trend of society, there are more and more people devoting themselves to the society with altruistic heart. Well understanding the characteristics of volunteers, and bring the professional specialty into full play to service the public is as important as nowadays. This study is to discuss the development and circumstances of the school sports volunteer team with literature analysis and interview. This study probed into the definitions and classifications of organization capital and spilt into four dimensions such as organizational culture, leadership, integration, and the team's conception. The purpose of the study lies in examining the feasibility of school sport volunteer team with the viewpoint of organization capital and hope the research can be the reference for the schools to build the organizational capital of the school sports volunteer team.