With the advent of the era of knowledge economy, the importance of intellectual capital has gradually reached to a consensus. Intellectual capital compared to financial and physical assets is a kind of intangible assets. It included in human capital, structural capital and social capital. In this study, from the human capital point of view, I tried to explore the current situation of the school sports volunteer team. Through literature analysis and the in-depth interviews, I found that the human capital on the school sports volunteer team included in four dimensions, such as sports volunteers' vision and leadership, service attitude, professional knowledge and skills, and innovation abilities. In this study, through interviewing, discussing, summing up the conclusions, I made some recommendations and hope the research will be the reference for the operation of the human capital on school sports volunteer teams.