As the tourist market has been booming out for years, the entrepreneurs in the travel sectors have been devoted to enhancing talent development and working performance related for employees so that they may enforce the working effectiveness for the organization. Hence, the study namely is aiming at exploring the employees and employers' perception on brilliant quotient (BQ) and work performance at Consolidated travel agencies and A-Class travel agencies in Kaohsiung City and Chia-Yi City; furthermore, the relationship between BQ and work performance would be discussed in this study. The findings are: 1) It is found in this study that BQ is highly correlated to work performance on employees and employers' perceptions. 2) Through multiple-regression analysis, it is found in this study that "Brilliant Quotient (BQ)" could highly influence on work performance. For the suggestions, the researchers are proposing that the entrepreneurs in the travel sectors may utilize soft power development and training programs to motivate self-perception and potential talents for employees and employers in the travel services in order to strengthen the organizational effectiveness.