In the previous literature, the study of deviant behavior often aims at teenagers in school and those in a reformatory as the main subject, and puts less emphasis on elementary pupils who violate the law. In addition, the factors of ethics and values are rarely put into consideration in the study of deviant behavior. This study uses the data from the study of the cause of children and teenagers law violation (1996) by Chuen-Jim Sheu、Huang, Frank Fu-Yuan、Hou,Chung-Weun、Xie, Wen-Yan、Zhou, De-Zhang、Mon, and Wei-Teh, commissioned by National Youth Commission, as main sources for analysis. Based on the data collected through questionnaires distributed to 513 pupils who are fifth or sixth graders and who violated the law before, the study tries to use the socialization process of fifth and sixth graders as the main factor to discuss how the external social control and intrinsic value affect children’s misbehaviors. The results demonstrate: 1. The factor of different backgrounds shows significant differences in external social control and intrinsic value and misbehaviors. 1-1 Girls in the items of “family control”、 “school control”、 inner “traditional value” belief are significantly higher than boys ,while in the items of “peer control” 、 inner “opportunistic thinking” and “misbehaviors”, boys are much more significant than girls. 1-2 Age difference at the level of “inappropriate place” and “misbehaviors” in peer control shows significantly correlated, and the significance in six grade is higher than in fifth grade. 1-3 Among bi-parental family、re-organized family and single-parental family, “family control” in the bi- parental family is the strongest; “peer control ”and “misbehaviors” in the re-organized family is significant than other types of family, and the research shows that the bi-parental family has the fewest “misbehaviors”. 1-4 low self -control in the “family control” and “school control” is negatively correlated, but low self- control in the “misbehaviors” 、 “peer control” shows positive correlation. 2. The factors of intrinsic value and external social control are relevant to children’s misbehaviors . The factors of family, school and traditional value and misbehaviors are negatively correlated, while the factors of peer pressure and speculation and misbehaviors are positively correlated. 3. The factors of intrinsic value and external social control can predict children’s misbehaviors. According to Stepwise Regression Procedure, the factor of environment, parent-child relationship, traditional values, speculation, companionship, and teacher-student relationship can predict children’s misbehaviors. 4. The enlightenment for the theory of crime The results show that the control and judgment of the intrinsic value have formed when pupils reach fifth and sixth grade. Besides of peer control, the influence of school and family supervision、the ability of self inner regulation and behavior control seems more direct and powerful and outer control. Therefore, this conclusion proves the self-control theory and moral development theory that family education and school education can dominate pupils’ behavior best before ten when self-control, personal value system and moral judgments are formed.