本研究係以射頻反應式磁控濺鍍的方法成長鋁/氮化鋁(Al/AlN)於藍寶石基板上,再以二次陽極處理的方式,使鋁薄膜氧化產生孔洞的陽極氧化鋁(anodic aluminium oxide;AAO)膜並觀察其表面的孔洞結構。在完成AAO/AlN/sapphire表面結構觀察後,運用AAO薄膜當作光罩,以電漿蝕刻的方式蝕刻AlN產生孔洞結構,製備出孔洞直徑為80~120nm左右的奈米孔洞的AlN薄膜,其孔洞間距約150~180nm。 最後將奈米孔洞AlN薄膜當做緩衝層,在上面磊晶GaN-based LED元件。實驗結果顯示,奈米孔洞AlN薄膜當做緩衝層,於20mA電流注入下,對照沒有奈米孔洞的單純AlN薄膜當做緩衝層GaN-bsaed LED可提升約提升38.2%的光輸出功率,而80mA也有32.9%的提升,大幅提升了發光二極體的效能。
This work discusses AlN nanoporous buffer layer prepared by anodic aluminum oxide (AAO) process for GaN-based light-emitting diode (LED) applications. After AAO process, the mean pore spacing and pore diameter of the AlN nanoporous buffer layer were in the range of 150 ~ 180 nm and 80 ~ 120 nm, respectively. The light output power of the GaN-based LED with an AlN nanoporous buffer layer was higher about 38.2% than that of the GaN-based LED without an AlN nanoporous buffer layer at an injection current of 20 mA. At aninjection current of 80 mA, only about 32.9% of enhancement factor on light extraction was obtained.