高效率壓電厚膜氣膠沉積製程設備之開發

Development of High Efficiency Aerosol Deposition Apparatus for Piezoelectric Ceramic Thick Film

郭昱均(Yu-Chun Kuo)

指導教授 ： 吳文中

國立臺灣大學/工學院/工程科學及海洋工程學研究所/碩士(2021年)

https://doi.org/10.6342/NTU202100557

摘要

氣膠沉積法因為具有相對鍍率高、沉積出的厚膜品質高和對製程環境要求低等特性，因此相當適合應用於沉積壓電厚膜和壓電元件製程中。在本研究中，我們以含有螺旋桿送粉設備的氣膠產生系統為基礎開發不同於以往的氣膠沉積製程設備，利用螺旋桿送粉設備將壓電粉末輸送進系統中進而讓壓電粉末和載體空氣混合形成氣膠，讓製程設備更適合未來將氣膠沉積製程設備往自動化發展。以本研究開發之氣膠沉積製程設備並在通入載體空氣流率5000 SCCM的情況下，重複噴塗30次可以沉積出膜厚約1.71 μm的壓電厚膜；將壓電厚膜經過520℃高溫退火處理3小時後進行鐵電分析得知本研究製備的壓電厚膜之殘餘極化量約為19.52 μC/cm2，此鐵電分析結果證實本研究製備之壓電厚膜具有相當程度的鐵電特性，細部實驗設計與研究成果將於本論文中說明。

關鍵字

氣膠沉積法 ； 壓電厚膜 ； 鋯鈦酸鉛 ； 氣膠產生系統 ； 螺旋桿輸送系統

並列摘要

The aerosol deposition (AD) method has the characteristics of high-speed deposition rate, low process environment restriction and the high ability to deposit high quality thick film in comparison with conventional thin-film/thick-film method or thermal spray coating technology. In this study, a new AD apparatus including an aerosol generator with screw feeder has been developed. The AD apparatus developed in this study has higher potential to be automatic in the future than previous apparatus. With the current AD apparatus set as 5000 SCCM carrier gas flow rate, 1.71 um of PZT thick film can be successfully deposited on a stainless steel substrate by PZT aerosol spraying repeatedly for 30 times. The PZT thick film after the annealing process is also confirmed to have ferroelectric property by ferroelectric hysteresis measurement and analysis. The experimental result also shows that the current AD apparatus has the feasibility to fabricate PZT thick film.

並列關鍵字

aerosol deposition method ； piezoelectric thick film ； lead zirconate titanate ； PZT ； aerosol generator ； screw feeder

參考文獻

[1] I. Kanno, "Piezoelectric MEMS: Ferroelectric thin films for MEMS applications," Japanese Journal of Applied Physics, vol. 57, no. 4, p. 040101, 2018.

[2] P. Muralt, R. G. Polcawich, and S. Trolier-McKinstry, "Piezoelectric thin films for sensors, actuators, and energy harvesting," MRS bulletin, vol. 34, no. 9, pp. 658-664, 2009.

[3] S. Priya, J. Ryu, C. S. Park, J. Oliver, J. J. Choi, and D. S. Park, "Piezoelectric and magnetoelectric thick films for fabricating power sources in wireless sensor nodes," Sensors, vol. 9, no. 8, pp. 6362-6384, 2009.

[4] G. Yi, Z. Wu, and M. Sayer, "Preparation of Pb (Zr, Ti) O3 thin films by sol gel processing: Electrical, optical, and electro‐optic properties," Journal of Applied Physics, vol. 64, no. 5, pp. 2717-2724, 1988.

[5] D. Barrow, T. Petroff, R. Tandon, and M. Sayer, "Characterization of thick lead zirconate titanate films fabricated using a new sol gel based process," Journal of Applied Physics, vol. 81, no. 2, pp. 876-881, 1997.